Überblick

Open Access

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Peer Reviewed

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Abstract

• Two solid solutions exist in the system CuMoO4/ZnMoO4: Cu1-xZnxMoO4 with x=0 to x=0.15 and x=0.20 bis x=1, respectively Single crystals of Cu1-xZnxMoO4 were obtained by chemical vapor transport in the temperature gradient 973K-->,873K using Cl-2, Br-2 or NH4Cl as transport agents. No difference of the Cu/Zn ratio between source and sink was observed for the transport agents Cl-2 and NH4Cl. A slight shift to higher Zn amounts was observed for single crystals of Cu1-xZnxMoO4 grown using, Br-2 as transport agent. The experimental results were compared with results of model calculations.

authors

• Udo Steiner
• Dabritz, S
• Reichelt, W

Veröffentlichungszeitpunkt

• Januar 1, 2003

veröffentlicht in

• Zeitschrift für anorganische und allgemeine Chemie (1950), Vol.629(1), pp. 116-122  Zeitschrift